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Understanding Stability and Rheology in Lithium Battery Slurry Suspensions

2025-01-14

Exploring the Dynamics of Lithium battery slurry Suspensions

The Role of Charged Particles in Lithium Battery Slurry

In lithium battery slurry suspensions, particle surfaces are always charged. This charge leads to the formation of an electric double layer on the particle surface, comprising an adsorption layer and a diffusion layer. The crucial aspect here is the zeta potential, which is the potential difference from the adsorption layer to the inside of the particles. A high zeta potential in lithium battery slurry allows particles to maintain sufficient distance to counteract van der Waals forces, thereby enhancing suspension stability. Conversely, a low zeta potential results in reduced inter-particle repulsion, leading to particle attraction and agglomeration.

Factors Affecting Lithium Battery Slurry Stability

The dispersed phase content, pH value, and inorganic salt concentration in the lithium battery slurry influence the thickness of the electric double layer. These factors alter the zeta potential and reduce electrostatic repulsion, affecting the slurry’s stability.

Adsorption Mechanisms in Lithium Battery Slurry

Adsorption plays a vital role in lithium battery slurry suspensions, defining how substances adhere to surfaces within the slurry. The surfactant’s adsorption mode, strength, and amount determine the interaction with dispersed particles. Within the lithium battery slurry, surfactants adhere to particle interfaces, creating a dense layer that increases steric hindrance among particles. This spatial stabilization enhances the anti-coalescence stability of the slurry.

Influencing Surfactant Adsorption in Lithium Battery Slurry

The type and dosage of surfactant, along with molecular weight, system pH, salt concentration, and temperature, critically influence surfactant adsorption in lithium battery slurry suspensions. These factors determine the dispersion efficiency within the slurry system, significantly impacting performance.

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